Tickets for Sunday's game at the VBS Community Stadium are available here, with prices starting at just £5.00 for Under-16s.
Palace Women are in Group E of the League Cup this season, along with Aston Villa, Charlton Athletic and Tottenham Hotspur.
Having narrowly missed out on the knockout stages last season, head coach Laura Kaminski and the team will be determined to go one stage further in this year's competition.
Palace faced Villa in the first fixture of the 2024/25 competition, losing 2-0 away at the Bescot Stadium in early October.